Multiscale transparent electrode architecture for efficient light management and carrier collection in solar cells.
Identifieur interne : 000B93 ( Main/Exploration ); précédent : 000B92; suivant : 000B94Multiscale transparent electrode architecture for efficient light management and carrier collection in solar cells.
Auteurs : RBID : pubmed:22332666English descriptors
- KwdEn :
- MESH :
- chemistry : Nanostructures.
- instrumentation : Nanotechnology.
- ultrastructure : Nanostructures.
- Electric Power Supplies, Electrodes, Equipment Design, Equipment Failure Analysis, Light, Particle Size, Refractometry, Scattering, Radiation, Solar Energy.
Abstract
The challenge for all photovoltaic technologies is to maximize light absorption, to convert photons with minimal losses into electric charges, and to efficiently extract them to the electrical circuit. For thin-film solar cells, all these tasks rely heavily on the transparent front electrode. Here we present a multiscale electrode architecture that allows us to achieve efficiencies as high as 14.1% with a thin-film silicon tandem solar cell employing only 3 μm of silicon. Our approach combines the versatility of nanoimprint lithography, the unusually high carrier mobility of hydrogenated indium oxide (over 100 cm(2)/V/s), and the unequaled light-scattering properties of self-textured zinc oxide. A multiscale texture provides light trapping over a broad wavelength range while ensuring an optimum morphology for the growth of high-quality silicon layers. A conductive bilayer stack guarantees carrier extraction while minimizing parasitic absorption losses. The tunability accessible through such multiscale electrode architecture offers unprecedented possibilities to address the trade-off between cell optical and electrical performance.
DOI: 10.1021/nl203909u
PubMed: 22332666
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Le document en format XML
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<author><name sortKey="Boccard, Mathieu" uniqKey="Boccard M">Mathieu Boccard</name>
<affiliation wicri:level="1"><nlm:affiliation>Institute of Microengineering (IMT), Photovoltaics and Thin Film Electronics Laboratory, Ecole Polytechnique Fédérale de Lausanne (EPFL), Rue A.-L. Breguet 2, CH-2000 Neuchâtel, Switzerland. mathieu.boccard@epfl.ch</nlm:affiliation>
<country xml:lang="fr">Suisse</country>
<wicri:regionArea>Institute of Microengineering (IMT), Photovoltaics and Thin Film Electronics Laboratory, Ecole Polytechnique Fédérale de Lausanne (EPFL), Rue A.-L. Breguet 2, CH-2000 Neuchâtel</wicri:regionArea>
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<author><name sortKey="Battaglia, Corsin" uniqKey="Battaglia C">Corsin Battaglia</name>
</author>
<author><name sortKey="H Nni, Simon" uniqKey="H Nni S">Simon Hänni</name>
</author>
<author><name sortKey="S Derstr M, Karin" uniqKey="S Derstr M K">Karin Söderström</name>
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<author><name sortKey="Escarre, Jordi" uniqKey="Escarre J">Jordi Escarré</name>
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<author><name sortKey="Nicolay, Sylvain" uniqKey="Nicolay S">Sylvain Nicolay</name>
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<author><name sortKey="Meillaud, Fanny" uniqKey="Meillaud F">Fanny Meillaud</name>
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<author><name sortKey="Despeisse, Matthieu" uniqKey="Despeisse M">Matthieu Despeisse</name>
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<author><name sortKey="Ballif, Christophe" uniqKey="Ballif C">Christophe Ballif</name>
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<term>Equipment Failure Analysis</term>
<term>Light</term>
<term>Nanostructures (chemistry)</term>
<term>Nanostructures (ultrastructure)</term>
<term>Nanotechnology (instrumentation)</term>
<term>Particle Size</term>
<term>Refractometry</term>
<term>Scattering, Radiation</term>
<term>Solar Energy</term>
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<term>Electrodes</term>
<term>Equipment Design</term>
<term>Equipment Failure Analysis</term>
<term>Light</term>
<term>Particle Size</term>
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<front><div type="abstract" xml:lang="en">The challenge for all photovoltaic technologies is to maximize light absorption, to convert photons with minimal losses into electric charges, and to efficiently extract them to the electrical circuit. For thin-film solar cells, all these tasks rely heavily on the transparent front electrode. Here we present a multiscale electrode architecture that allows us to achieve efficiencies as high as 14.1% with a thin-film silicon tandem solar cell employing only 3 μm of silicon. Our approach combines the versatility of nanoimprint lithography, the unusually high carrier mobility of hydrogenated indium oxide (over 100 cm(2)/V/s), and the unequaled light-scattering properties of self-textured zinc oxide. A multiscale texture provides light trapping over a broad wavelength range while ensuring an optimum morphology for the growth of high-quality silicon layers. A conductive bilayer stack guarantees carrier extraction while minimizing parasitic absorption losses. The tunability accessible through such multiscale electrode architecture offers unprecedented possibilities to address the trade-off between cell optical and electrical performance.</div>
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<Article PubModel="Print-Electronic"><Journal><ISSN IssnType="Electronic">1530-6992</ISSN>
<JournalIssue CitedMedium="Internet"><Volume>12</Volume>
<Issue>3</Issue>
<PubDate><Year>2012</Year>
<Month>Mar</Month>
<Day>14</Day>
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<Title>Nano letters</Title>
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<ArticleTitle>Multiscale transparent electrode architecture for efficient light management and carrier collection in solar cells.</ArticleTitle>
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<Abstract><AbstractText>The challenge for all photovoltaic technologies is to maximize light absorption, to convert photons with minimal losses into electric charges, and to efficiently extract them to the electrical circuit. For thin-film solar cells, all these tasks rely heavily on the transparent front electrode. Here we present a multiscale electrode architecture that allows us to achieve efficiencies as high as 14.1% with a thin-film silicon tandem solar cell employing only 3 μm of silicon. Our approach combines the versatility of nanoimprint lithography, the unusually high carrier mobility of hydrogenated indium oxide (over 100 cm(2)/V/s), and the unequaled light-scattering properties of self-textured zinc oxide. A multiscale texture provides light trapping over a broad wavelength range while ensuring an optimum morphology for the growth of high-quality silicon layers. A conductive bilayer stack guarantees carrier extraction while minimizing parasitic absorption losses. The tunability accessible through such multiscale electrode architecture offers unprecedented possibilities to address the trade-off between cell optical and electrical performance.</AbstractText>
<CopyrightInformation>© 2012 American Chemical Society</CopyrightInformation>
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<AuthorList CompleteYN="Y"><Author ValidYN="Y"><LastName>Boccard</LastName>
<ForeName>Mathieu</ForeName>
<Initials>M</Initials>
<Affiliation>Institute of Microengineering (IMT), Photovoltaics and Thin Film Electronics Laboratory, Ecole Polytechnique Fédérale de Lausanne (EPFL), Rue A.-L. Breguet 2, CH-2000 Neuchâtel, Switzerland. mathieu.boccard@epfl.ch</Affiliation>
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<MeshHeading><DescriptorName MajorTopicYN="Y">Solar Energy</DescriptorName>
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